Regioselective Enzymatic Carboxylation of Bioactive (Poly)phenols

BioChem - DOS

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논문

Regioselective Enzymatic Carboxylation of Bioactive (Poly)phenols

학술지

Advanced synthesis & catalysis

저자명

Plasch, Katharina; Resch, Verena; Hitce, Julien; Popłoń ski, Jarosław; Faber, Kurt; Glueck, Silvia M.

초록

AbstractIn order to extend the applicability of the regioselective enzymatic carboxylation of phenols, the substrate scope of o‐benzoic acid (de)carboxylases has been investigated towards complex molecules with an emphasis on flavouring agents and polyphenols possessing antioxidant properties. o‐Hydroxycarboxylic acid products were obtained with perfect regioselectivity, in moderate to excellent yields. The applicability of this method was proven by the regioselective bio‐carboxylation of resveratrol on a preparative scale with 95% yield.

발행연도

2017

발행기관

John Wiley and Sons Inc.

라이선스

cc-by

ISSN

1615-4150

ISSN

1615-4169

권

359