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Continuous hydrogen production from cofermentation of sugarcane vinasse and cheese whey in a thermophilic anaerobic fluidized bed reactor

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    • 바이오플라스틱
      1. 고무
      2. 플라스틱
    • 바이오정밀화학
      1. 용매
      2. 화학제품
      3. 연료
      4. 기타
    • 화장품용 기능성소재
      1. 계면활성제⁄증점제
    • 의료용 화학소재
      1. 치료제
      2. 식품첨가제
논문

Continuous hydrogen production from cofermentation of sugarcane vinasse and cheese whey in a thermophilic anaerobic fluidized bed reactor

학술지

International journal of hydrogen energy

저자명

Ramos, Lucas Rodrigues; Silva, Edson Luiz

초록

<P><B>Abstract</B></P> <P>The co-fermentation of vinasse and cheese whey (CW) was evaluated in this study by using two thermophilic (55&deg; C) anaerobic fluidized bed reactors (AFBRs). In AFBR using vinasse and CW (AFBR-V-CW), the CW was added in increasing proportions (2, 4, 6, 8, and 10 g COD.L<SUP>&minus;1</SUP>) to vinasse (10 g COD.L<SUP>&minus;1</SUP>) to assess the advantage of adding CW to vinasse. By decreasing the hydraulic retention time (HRT) from 8 h to 1 h in AFBR-V, maximum hydrogen yield (HY), production rate (HPR), and H<SUB>2</SUB> content (H<SUB>2</SUB>%) of 1.01 &plusmn; 0.06 mmol H<SUB>2</SUB>.g COD<SUP>&minus;1</SUP>, 2.54 &plusmn; 0.39 L H<SUB>2</SUB>.d<SUP>&minus;1</SUP>.L<SUP>&minus;1</SUP>, and 47.3 &plusmn; 2.9%, respectively, were observed at an HRT of 6 h. The increase in CW concentration to values over 2 g COD.L<SUP>&minus;1</SUP> in AFBR-V-CW decreased the HY, PVH, and H<SUB>2</SUB>%, with observed maximum values of 0.82 &plusmn; 0.07 mmol H<SUB>2</SUB>.g COD<SUP>&minus;1</SUP>, 1.41 &plusmn; 0.24 L H<SUB>2</SUB>.d<SUP>&minus;1</SUP>.L<SUP>&minus;1</SUP>, and 55.5 &plusmn; 3.7%, respectively, at an HRT of 8 h. The comparison of AFBR-V-CW and AFBR-V showed that the co-fermentation of vinasse with 2 g COD.L<SUP>&minus;1</SUP> of CW increased the HPR, H<SUB>2</SUB>%, and HY by 117%, 68%, and 82%, respectively.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Addition of cheese whey (2 g COD.L<SUP>&minus;1</SUP>) to vinasse increased H<SUB>2</SUB> yield (HY) by 82%. </LI> <LI> Excess cheese whey concentration decreased HY by lack of nitrogen. </LI> <LI> Decrease in hydraulic retention time (HRT < 6 h) decreased HY and production rate (HPR). </LI> <LI> Maximum HY (1.01 &plusmn; 0.06 mmol H<SUB>2</SUB>.g COD<SUP>&minus;1</SUP>) was observed in HRT of 6 h. </LI> <LI> H<SUB>2</SUB> production in both reactors was dominated by acetic and butyric pathways. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

발행연도

2018

발행기관

Elsevier

ISSN

0360-3199

ISSN

1879-3487

43

29

페이지

pp.13081-13089

주제어

Cheese whey; Sugar cane vinasse; Thermophilic fermentation; Cofermentation; Hydraulic retention time

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논문; 2018-07-01

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