Enzyme cascade reactions: synthesis of furandicarboxylic acid (FDCA) and carboxylic acids using oxidases in tandem

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논문

Enzyme cascade reactions: synthesis of furandicarboxylic acid (FDCA) and carboxylic acids using oxidases in tandem

학술지

Green chemistry : an international journal and green chemistry resource : GC

저자명

McKenna, Shane M.; Leimkü hler, Silke; Herter, Susanne; Turner, Nicholas J.; Carnell, Andrew J.

초록

A one-pot tandem enzyme reaction using galactose oxidase M3–5 and aldehyde oxidase PaoABC was used to convert hydroxymethylfurfural (HMF) to the pure bioplastics precursor FDCA in 74% isolated yield. A range of alcohols was also converted to carboxylic acids in high yield under mild conditions. Graphic AbstractThree enzymes are combined under mild conditions for the preparative scale oxidation of HMF to FDCA and a range of 10 alcohols. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c5gc00707k'>

발행연도

2015

발행기관

The Royal Society of Chemistry

ISSN

1463-9262

ISSN

1463-9270

권

호

페이지

pp.3271-3275