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Improved cathode for high efficient microbial-catalyzed reduction in microbial electrosynthesis cells

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논문

Improved cathode for high efficient microbial-catalyzed reduction in microbial electrosynthesis cells

학술지

Physical chemistry chemical physics : PCCP

저자명

Nie, Huarong; Zhang, Tian; Cui, Mengmeng; Lu, Haiyun; Lovley, Derek R.; Russell, Thomas P.

초록

<P>Microbial electrosynthesis cells (MECs) are devices wherein microorganisms can electrochemically interact with electrodes, directly donating or accepting electrons from electrode surfaces. Here, we developed a novel cathode by using nickel nanowires anchored to graphite for the improvement of microbial-catalyzed reduction in MEC cathode chamber. This porous nickel-nanowire-network-coated graphite electrode increased the interfacial area and interfacial interactions between the cathode surface and the microbial biofilm. A 2.3 fold increase in bio-reduction rate over the untreated graphite was observed. Around 282 mM day<SUP>&minus;1</SUP> m<SUP>&minus;2</SUP> of acetate resulting from the bio-reduction of carbon dioxide by <I>Sporomusa</I> was produced with 82 &plusmn; 14% of the electrons consumed being recovered in acetate.</P><BR><BR><P>Graphic Abstract</P><P>A novel cathode, nickel nanowire coated graphite, was developed to increase reduction rate of CO<SUB>2</SUB> in microbial electrosynthesis cells.<BR><IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c3cp52697f'><BR></P>

발행연도

2013

발행기관

The Royal Society of Chemistry

ISSN

1463-9076

ISSN

1463-9084

15

34

페이지

pp.14290-14294

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1 2023-12-11

논문; 2013-01-01

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