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Metabolic engineering of the 2-ketobutyrate biosynthetic pathway for 1-propanol production in Saccharomyces cerevisiae

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논문

Metabolic engineering of the 2-ketobutyrate biosynthetic pathway for 1-propanol production in Saccharomyces cerevisiae

학술지

Microbial cell factories

저자명

Nishimura, Yuya; Matsui, Terumi; Ishii, Jun; Kondo, Akihiko

초록

<P><B>Background</B></P><P>To produce 1-propanol as a potential biofuel, metabolic engineering of microorganisms, such as <I>E. coli</I>, has been studied. However, 1-propanol production using metabolically engineered <I>Saccharomyces cerevisiae</I>, which has an amazing ability to produce ethanol and is thus alcohol-tolerant, has infrequently been reported. Therefore, in this study, we aimed to engineer <I>S. cerevisiae</I> strains capable of producing 1-propanol at high levels.</P><P><B>Results</B></P><P>We found that the activity of endogenous 2-keto acid decarboxylase and alcohol/aldehyde dehydrogenase is sufficient to convert 2-ketobutyrate (2&nbsp;KB) to 500&nbsp;mg/L 1-propanol in yeast. Production of 1-propanol could be increased by: (i) the construction of an artificial 2&nbsp;KB biosynthetic pathway from pyruvate via citramalate (<I>cimA</I>); (ii) overexpression of threonine dehydratase (<I>tdcB</I>); (iii) enhancement of threonine biosynthesis from aspartate (<I>thrA</I>, <I>thrB</I> and <I>thrC</I>); and (iv) deletion of the <I>GLY1</I> gene that regulates a competing pathway converting threonine to glycine. With high-density anaerobic fermentation of the engineered <I>S. cerevisiae</I> strain YG5C4231, we succeeded in producing 180&nbsp;mg/L 1-propanol from glucose.</P><P><B>Conclusion</B></P><P>These results indicate that the engineering of a citramalate-mediated pathway as a production method for 1-propanol in <I>S. cerevisiae</I> is effective. Although optimization of the carbon flux in <I>S. cerevisiae</I> is necessary to harness this pathway, it is a promising candidate for the large-scale production of 1-propanol.</P><P><B>Electronic supplementary material</B></P><P>The online version of this article (10.1186/s12934-018-0883-1) contains supplementary material, which is available to authorized users.</P>

발행연도

2018

발행기관

BioMed Central

라이선스

cc-by

ISSN

1475-2859

17

페이지

pp.38

주제어

1-Propanol; Yeast; S. cerevisiae; Fermentation; 2-Ketobutyrate

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1 2023-12-11

논문; 2018-03-09

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