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Photo- and Stress-Induced Bending of (E)-1,2-Bis(pyridinium-4-yl)ethene Dinitrate Crystals

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논문

Photo- and Stress-Induced Bending of (E)-1,2-Bis(pyridinium-4-yl)ethene Dinitrate Crystals

학술지

Chemistry : a European journal

저자명

Kusumoto, Sotaro; Wakabayashi, Kaede; Rakumitsu, Kenta; Harrowfield, Jack; Kim, Yang; Koide, Yoshihiro

초록

<P><B>Abstract</B><P>We report on the elastic and photodynamic properties of (<I>E</I>)&#x2010;1,2&#x2010;bis(pyridinium&#x2010;4&#x2010;yl)ethene dinitrate [H2Ebpe](NO3)2, whose needle&#x2010;like crystals can be reversibly deformed by applying external mechanical stress. The macro&#x2010;scale mechanical properties of [H2Ebpe](NO3)2 crystals were quantified by a three&#x2010;point bending test, which gave a stress&#x2010;strain curve with an elastic modulus of 1.18 GPa, and its values are lower than those of other flexible elastic organic crystals. It can also be reversibly bent through the [2+2] cycloaddition reaction of the olefin moiety, depending on the direction of UV irradiation.</P></P>

발행연도

2024

발행기관

Wiley (John WileySons)

ISSN

0947-6539

ISSN

1521-3765

30

40

페이지

pp.e202401564

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1 2023-12-11

논문; 2024-05-26

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