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Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent

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논문

Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent

학술지

Industrial crops and products

저자명

Peleteiro, S.; da Costa Lopes, A.M.; Garrote, G.; Bogel-Lukasik, R.; Parajo, J.C.

초록

Xylose was converted into furfural operating in a medium containing the acidic ionic liquid (AIL) 1-butyl-3-methylimidazolium hydrogen sulfate, in the presence of toluene as a co-solvent. No catalytic species different from the AIL were needed for furfural production from xylose. Operating at 100-140<SUP>o</SUP>C for 15-480min in media containing 10g xylose/100g AIL and 2-4g toluene/g (AIL+xylose), most furfural generated in the AIL phase was transferred to the co-solvent, limiting the losses caused by undesired side reactions. Operating under optimal conditions (140<SUP>o</SUP>C for 240min using 4.4g toluene/g initial AIL phase), xylose was almost completely consumed, and furfural was obtained at 73.8% of the stoichiometric yield.

발행연도

2015

발행기관

Elsevier

ISSN

0926-6690

77

페이지

pp.163-166

주제어

Acidic ionic liquid; Biphasic system; 1-Butyl-3-methylimidazolium hydrogen sulfate; Toluene; Furfural; Xylose

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1 2023-12-11
2 2023-12-11

논문; 2015-12-01

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