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The use of thermochemical pretreatments to improve the anaerobic biodegradability and biochemical methane potential of the sugarcane bagasse

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논문

The use of thermochemical pretreatments to improve the anaerobic biodegradability and biochemical methane potential of the sugarcane bagasse

학술지

Chemical engineering journal

저자명

Costa, A.G.; Pinheiro, G.C.; Pinheiro, F.G.C.; Dos Santos, A.B.; Santaella, S.T.; Leitao, R.C.

초록

Lignocellulosic material can be used as biomass for power generation via biogas if it is pretreated to improve the anaerobic hydrolysis step, by either solubilising the hemicellulose (total reducing groups, TRG) or removing lignin (Lig), with consequent exposition of the cellulose fibre to anaerobic degradation. We evaluated the effects of acid, alkaline, and hydrothermal pretreatments on sugarcane bagasse to increase its anaerobic biodegradability and biochemical methane potential (BMP). The highest sugar production (31.14gTRG/gsubstrate) was achieved with the acid pretreatment in 6.4min at 138<SUP>o</SUP>C, with a HCl concentration of 0.63M, and the highest lignin removal (23.24gLig/gsubstrate) was found with the alkaline pretreatment after 47min at 184<SUP>o</SUP>C and a NaOH concentration of 0.8M. However, the best values of BMP (197.5LCH<SUB>4</SUB>/kgsubstrate) and anaerobic biodegradability (27.4%) were achieved by the hydrothermal pretreatment after 10min at 200<SUP>o</SUP>C, which was sufficient to generate power of 6.8MJ/kgsubstrate. The results showed that the methane derived from the anaerobic digestion of these hydrolysates produced less energy than the direct burning of the dry bagasse. Thus, the recovered lignin, with its high added-value, may be used to improve environmental sustainability and profitability of the process. In this case, the alkaline pretreatment extracted 80.2% of the lignin present in the bagasse, and the hydrolysate could generate 313.4LCH<SUB>4</SUB>/kgsubstrate.

발행연도

2014

발행기관

Elsevier

ISSN

1385-8947

248

페이지

pp.363-372

주제어

Anaerobic biodegradability; Hydrolysis; Lignocellulosic waste; Pretreatment; Sugar and ethanol industry

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논문; 2014-07-01

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