초록
<P><B>Abstract</B></P> <P>An anaerobic sequencing batch biofilm reactor (AnSBBR) treating a mixture of dairy industry wastewater and biodiesel production wastewater (co-digestion of whey with glycerin) was applied to hydrogen production. The influence of fed-batch and batch mode, cycle time and interactions effects between influent concentration and cycle time (2, 3 and 4 h) over the organic loading rate were assessed in order to obtain a sensitivity analysis for important operational variables to the reactor. It was possible to find an optimal cycle time of 3 h with an influent concentration of 7000 mgCOD L<SUP>−1</SUP> (molar productivity 129.0 molH<SUB>2</SUB> m<SUP>−3</SUP> d<SUP>−1</SUP> and yield 5.4 molH<SUB>2</SUB> kgCOD<SUP>−1</SUP>). Reactor operation in fed-batch mode allowed higher hydrogen production rates. Increasing the influent concentration (with a constant cycle time) was better for the hydrogen production process than decreasing the cycle length (with a constant influent concentration), which means that these two parameters have different weights in the organic loading rate. The best operational conditions produce hydrogen via acetic, butyric and valeric acids similarly. The system is able to produce 1.3 kJ per gram of COD applied.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Co-digestion of whey with glycerin was applied in an AnSBBR for H<SUB>2</SUB> production. </LI> <LI> Interactions between influent concentration and cycle time over AVOL were assessed. </LI> <LI> It is best to increase influent concentration than to reduce cycle time. </LI> <LI> Reactor operation in fed-batch mode allowed higher hydrogen production rates. </LI> <LI> The system's energy recovery is up to 1.3 kJ per gram of COD applied. </LI> </UL> </P>