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Carbon as a Simple Support for Redox Biocatalysis in Continuous Flow

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논문

Carbon as a Simple Support for Redox Biocatalysis in Continuous Flow

학술지

Organic process research & development

저자명

Poznansky, Barnabas; Thompson, Lisa A.; Warren, Sarah A.; Reeve, Holly A.; Vincent, Kylie A.

초록

<P>A continuous packed bed reactor for NADH-dependent biocatalysis using enzymes co-immobilized on a simple carbon support was optimized to 100% conversion in a residence time of 30 min. Conversion of pyruvate to lactate was achieved by co-immobilized lactate dehydrogenase and formate dehydrogenase, providing in situ cofactor recycling. Other metrics were also considered as optimization targets, such as low E factors between 2.5-11 and space-time yields of up to 22.9 g L<SUP>-1</SUP> h<SUP>-1</SUP>. The long-term stability of the biocatalytic reactor was also demonstrated, with full conversion maintained over more than 30 h of continuous operation.</P><BR>[FIG OMISSION]</BR>

발행연도

2020

발행기관

American Chemical Society

라이선스

cc-by

ISSN

1083-6160

ISSN

1520-586x

24

10

페이지

pp.2281-2287

주제어

biocatalysis; flow chemistry; cofactor recycling; immobilized enzyme; packed bed

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논문; 2020-01-31

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