Redox-Neutral 1,4-Dicarbonfunctionalization of 1,3-Butadiene by Merging Photoredox and Nickel Catalysis

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  1. 고무

논문

Redox-Neutral 1,4-Dicarbonfunctionalization of 1,3-Butadiene by Merging Photoredox and Nickel Catalysis

학술지

Organic letters

저자명

Ding, Du; Fan, Lian-Feng; Han, Zhi-Yong; Wang, Pu-Sheng

초록

<P>The diverse functionalization of 1,3-butadiene provides wide applicability toward the synthesis of abundant and useful allylic compounds. Here, we describe a three-component and redox-neutral assembly of readily available C═X compounds, 1,3-butadiene, and various nucleophiles by merging photoredox and nickel catalysis, enabling the rapid synthesis of structurally diverse homoallyl amines and homoallylic alcohols.</P><BR>[FIG OMISSION]</BR>

발행연도

2023

발행기관

American Chemical Society

ISSN

1523-7060

권

호

페이지

pp.210-214

DOI

10.1021/acs.orglett.2c04060